[Bis(diphenylphosphino)methane-κ2 P,P′][bis(diphenylphosphinomethyl)diethoxysilane-κ2 P,P′]bis(dinitrogen)molybdenum(0) benzene 0.7-solvate
نویسندگان
چکیده
In the crystal structure of the title compound, [Mo(C(25)H(22)P(2))(C(30)H(34)O(2)P(2)Si)(N(2))(2)]·0.7C(6)H(6), the Mo atoms are coordinated by four P atoms and two N atoms in a distorted octa-hedral mode. The two C atoms of one of the two eth-oxy groups are disordered and were refined using a split model and site-occupation factors of 0.7:0.3. The crystal structure contains a benzene solvent mol-ecule with a site occupation of 70%.
منابع مشابه
Bis[μ-bis(diphenylphosphino)methane-κ2 P:P′]bis[(2,2′-bipyridine-κ2 N,N′)copper(I)] bis(tetrafluoroborate)
The centrosymmetric title compound, [Cu(2)(C(10)H(8)N(2))(2)(C(25)H(22)P(2))(2)](BF(4))(2), consists of discrete dinuclear cations and tetra-fluoro-borate anions. The two Cu(I) centers are bridged by the phosphine ligands to form an eight-membered ring. The Cu(I) center exhibits a tetra-hedral coordination as it is chelated by the N-heterocycle.
متن کاملBis[μ-1,2-bis(diphenylphosphino)methane-κ2 P:P′]bis[(η2-ethene)nickel(0)] toluene disolvate
In the title compound, [Ni(2)(C(2)H(4))(2)(C(25)H(22)P(2))(2)]·2C(7)H(8), each Ni atom is coordinated in a trigonal-planar geometry by two P atoms of the bridging 1,2-bis-(diphenyl-phosphino)methane (dppm) ligands and by the centroid of the double bond of an ethene ligand. An eight-membered ring comprising the two Ni atoms, four P atoms and the CH(2) groups of the two dppm ligands is thus forme...
متن کامل[1,2-Bis(diphenylphosphino)ethane]{2-[bis(diphenylphosphinomethyl)amino]pyridinium}fluoridohydrazidatomolybdenum(IV) bis(tetrafluoridoborate)
In the crystal structure of the title compound, [MoF(N(2)H(2))(C(31)H(29)N(2)P(2))(C(26)H(24)P(2))](BF(4))(2), each Mo atom is surrounded by four P atoms of one 1,2-bis-(diphenyl-phosphino)ethane and one 2-[bis-(diphenyl-phosphinometh-yl)amino]pyridinium ligand. The remaining binding sites of the distorted octa-hedron are occupied by a hydrazidate (NNH(2) (2-)) and a fluoride ligand. Two F atom...
متن کاملcatena-Poly[[[acetonitrilecopper(I)]-bis[μ-bis(diphenylphosphino)methane-κ2 P:P′]-copper(I)-μ-1,2-di-4-pyridylethene] bis(tetrafluoridoborate)]
The title dinuclear copper(I) complex, {[Cu(2)(C(2)H(3)N)(C(12)H(10)N(2))(C(25)H(22)P(2))(2)](BF(4))(2)}(n), contains 1,2-di-4-pyridyl-ethene, bis-(diphenyl-phosphino)methane and acetonitrile ligands. The two Cu atoms, one with an N(2)P(2) ligand set and the other with an NP(2) ligand set, are bridged by two bis-(diphenyl-phosphino)methane ligands, forming an eight-membered ring.
متن کامل[μ-N,N′-Bis(diphenylphosphinomethyl)benzene-1,4-diamine-κ2 P:P′]bis[(2,2′-bipyridine-κ2 N,N′)silver(I)] bis(perchlorate) acetone disolvate
The title complex, [Ag(2)(C(10)H(8)N(2))(2)(C(32)H(30)N(2)P(2))](ClO(4))(2)·2CH(3)COCH(3), is a centrosymmetric dimer with pairs of Ag(I) atoms bridged by N,N'-bis-(diphenyl-phosphinometh-yl)ben-zene-1,4-diamine ligands. In addition, each Ag(I) atom is coordin-ated by one chelating 2,2'-bipyridine ligand, giving a distorted trigonal coordination environment.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008